Materials and Methods: This study was
performed experimentally. In this study, the effect of pH, retention time,
adsorbent mass and initial concentrations of nickel ions have been evaluated.
The experimental isotherm data were analyzed using the Langmuir, Freundlich and
Temkin equations. Also, to determining the best adsorption kinetic model for
nickel ions onto acorn ashes, the pseudo first-order, pseudo second-order and
Elovich equations were used.
Results:
Experimental data indicated that the adsorption capacity was
dependent on pH of the solution, retention time, adsorbent mass and initial
nickel ions concentration. The optimum pH for adsorption of nickel ions was
7.0. With increasing of adsorbent mass and retention time, adsorption
efficiency increased while with increasing of initial nickel ions concentration,
adsorption efficiency decreased. The results showed that the experimental data
much better fit with the Freundlich isotherm. The best model for the adsorption
kinetic was shown with the pseudo-second-order kinetic model.
Conclusion: The present
study indicates that the Iranian acorn (Quercus persica) ashes can be used as
an effective and environmentally friendly biosorbent for the removal of nickel
(II) ions from aqueous solutions.
Key words: Heavy
metals, Adsorption, Nickel, Acorn ashes, Isotherms and kinetics
Funding:
This research
was funded by Yazd Shahid Sadoughi University of Medical Sciences.
Conflict
of interest: None
declared.
Ethical
approval: The
Ethics Committee of Yazd Shahid Sadoughi University of Medical Sciences
approved the study.
How to cite this
article: Zarei S, Dehvari M, Jamshidi B,
Sadani M. Investigation of Isotherm And Kinetic of Nickel Adsorption by Acorn Ashes
from Aqueous Solutions. J RafsanjanUniv Med Sci 2014 13(10): 897-908. [Farsi]
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