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URL: http://journal.rums.ac.ir/article-1-2280-en.html
Investigation of Sonochemical Oxidation Process in the Presence of SiO2, CuSO4 and Na2SO4 in Removal of Acid Black1 Azo Dye from Aqueous Solution
A.R. Rahmani[1], Z. Masoumi[2], A. Shabanlo2, S. Akbari2, H. Zolghadr nasab2, H. Almasi[3]
Received: 05/11/2014 Sent for Revision: 04/01/2015 Received Revised Manuscript: 04/02/2015 Accepted: 18/02/2015
Background and Objective: Acid Black 1 dye due to the presence of benzene ring, toxicity, mutagenicity, carcinogenicity and non-degradability is one of the major dangers for human health and environment especially aquatic life. Hence, the removal of these compounds from polluted water and wastewater has been considered. This study has been investigated the removal of acid black1 azo dye from aqueous solution in the presence of SiO2, CuSO4 and Na2SO4.
Materials and Methods: In this experimental study the treatability of effluent polluted with reactive acid black 1 dye was investigated by using sonochemical oxidation in a reactor. The sample with the desired concentrations of dye (200-400 mg/L) in pH= 3-11 was prepared, also the required concentrations of silica, copper sulfate and sodium sulfate (25 to 100 mg/L) and S2O82- (1 to 10 mM/L) were flowed into the reactor intermittently. Ferrous sulfate as a source of ion (1 to 10 mM/L) was used.
Results: The results have showed that 100% of the dye after 45 min at pH 3, 7.5 mM/L persulfate and concentration of 100 mg/ L in presence of 3 additives was removed. The dye removal in above condition decreased to 89.89% without the presence of additives. Also, the results showed that increasing the concentration of persulfate more than 10 mM/L no effect of removal of efficiency and the removal of the 64.56 percent decline.
Conclusion:The findings showed the combined process of ultrasonic and persulfate with the presence of 3 additives in optimal conditions of operation can be used as an acceptable option in the removal of dye in various industrial wastewater.
Key words: Removal of acid black 1 dye, Sonochemical process, Additive, Aqueous solution
Funding: This research was funded by Hamadan University of Medical Sciences.
Conflict of Interest: None declared.
Ethical approval: The Ethics Committee of Hamadan University of Medical Sciences approved the study.
How to cite this article: Rahmani AR, Masoumi Z, Shabanlo A, Akbari S, Zolghadr nasab H, Almasi H. Investigation of Sonochemical Oxidation Process in the Presence of SiO2, CuSO4 and Na2SO4 in Removal of Acid Black1 Azo Dye from Aqueous Solution. J RafsanjanUniv Med Sci 2015; 13(10): 1115-28. [Farsi]
- - Prof., Dept. of Environmental Health Engineering, Faculty of Health and Research Center for Health Sciences, Hamadan University of Medical Sciences, Hamadan, Iran
[2]- MSc in Environmental Health Engineering, School of Public Health, Hamadan University of Medical Sciences, Hamadan, Iran. Research Committee (SRC)
[3]- MSc Student of Environmental Health Engineering, School of Public Health, Hamadan University of Medical Sciences, Hamadan, Iran
(Corresponding Author), Tel: (081) 38381641, Fax: (081) 38381641, E-mail: h.almasi14@yahoo.com
Received: 2014/08/27 | Accepted: 2015/02/18 | Published: 2015/03/14
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